Tris(2,2 '-bipyridyl-N,N ')nickel(II) thiosulfate heptahydrate

Authors
Freire, E Baggio, S Mombru, A Baggio, R
Citation
E. Freire et al., Tris(2,2 '-bipyridyl-N,N ')nickel(II) thiosulfate heptahydrate, ACT CRYST C, 56, 2000, pp. 541-543
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
5
Pages
541 - 543
Database
ISI
SICI code
0108-2701(200005)56:<541:T''TH>2.0.ZU;2-F
Abstract
The structure of the title compound, [Ni(C10H8N2)(3)](S2O3). 7H(2)O, consis ts of monomeric Ni(bipy)(3)(2+) cations embedded in an anionic network made up of S2O32- ions and hydration water molecules. The structure presents th e unusual feature of two neighbouring thiosulfates approaching linearly hea d-to-head with an unusually short S ... S contact distance of 3.25 Angstrom .