Calcium(II) meso-2,3-diphenylsuccinate heptahydrate

Citation
G. Morin et al., Calcium(II) meso-2,3-diphenylsuccinate heptahydrate, ACT CRYST C, 56, 2000, pp. 544-545
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
5
Pages
544 - 545
Database
ISI
SICI code
0108-2701(200005)56:<544:CMH>2.0.ZU;2-R
Abstract
The title compound, [Ca(C16H12O4)(H2O)(6)]. H2O, adopts a conformation abou t the central CDC bond that places the two carboxylate groups in an anti or ientation. The crystal consists of layers of two-dimensional arrays of 2,3- diphenylsuccinate dianions which are linked by bridging Ca2+ cations. The u nit cell contains two Ca2+ cations in an unusual four-membered Ca-O-Ca-O ri ng in which the bridging O atoms belong to water molecules rather than carb oxylates, i.e. poly[[[di-mu-aqua-bis[pentaaquacalcium(II)]]-mu-(meso-2,3-di -phenylsuccinato-O:O')] succinate dihydrate].