Dichloro(tetrahydrofuran-O)-[(trimethylsilyl)amido-N]gallium(III)

Authors
Pickett, NL Just, O VanDerveer, DG Rees, WS
Citation
Nl. Pickett et al., Dichloro(tetrahydrofuran-O)-[(trimethylsilyl)amido-N]gallium(III), ACT CRYST C, 56, 2000, pp. 560-561
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
5
Pages
560 - 561
Database
ISI
SICI code
0108-2701(200005)56:<560:D>2.0.ZU;2-X
Abstract
The title compound, [GaCl2(C3H10NSi)(C4H8O)], is the tetrahydrofuran-coordi nated monomer of the previously structurally characterized dimer [GaN(H)SiM e3Cl2](2). The title compound consists of discrete monomeric molecules with two crystallographically independent molecules within the unit cell. The c rystal structure is composed of a Ga atom in a four-coordinate tetrahedral arrangement, with Ga-N distances of 2.025 (3) and 2.026 (3) Angstrom in the two independent molecules.