[1a(1a alpha,5 beta,9a alpha)]-1,1a,4,5,7,8,9,9a-Octahydro-3-hydroxy-1,1,2,5-tetra-methyl-7-methylene-6H-cyclopropa-[3,4]cyclohept[1,2-e]inden-6-one

Citation
Nt. Do Valle et al., [1a(1a alpha,5 beta,9a alpha)]-1,1a,4,5,7,8,9,9a-Octahydro-3-hydroxy-1,1,2,5-tetra-methyl-7-methylene-6H-cyclopropa-[3,4]cyclohept[1,2-e]inden-6-one, ACT CRYST C, 56, 2000, pp. 566-567
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
5
Pages
566 - 567
Database
ISI
SICI code
0108-2701(200005)56:<566:[ABA>2.0.ZU;2-7
Abstract
Interest in the title structure, C20H24O2, lies in the novel cis ring junct ion between the three- and seven-membered rings. This stereochemical arrang ement causes the methylene moiety and the cycloheptane ring to be twisted o ut of the plane of the aromatic ring. The cyclopropane ring is also twisted out of the plane of the aromatic system. The molecules are linked by an O- H ... O hydrogen bond [O ... O 2.741 (3) Angstrom].