Langmuir probe is an important tool to diagnose the plasma in radio frequen
cy (rf) glow discharge. A new method has been used to obtain the electron e
nergy distribution function in plasma by the numerical differentiation of t
he I-V probe characteristic. This method is based on Fourier transform and
could overcome the defects of other methods. In this way, the second deriva
tive signal of Langmuir probe I-V characteristic is obtained automatically
and accurately. The mean electron energy and electron concentrations in rf
glow discharge plasma in silane were obtained by Langmuir probe.