Emc. Reis-vasco et al., Mathematical modelling and simulation of pennyroyal essential oil supercritical extraction, CHEM ENG SC, 55(15), 2000, pp. 2917-2922
Pennyroyal essential oil was isolated by supercritical fluid extraction and
fractional separation. Extractions were performed at three different mean
particle sizes (0.3, 0.5 and 0.7 mm) and three CO2 flow rates (0.31, 0.43,
and 0.62 g/s) and at p = 100 bar and T = 323 K. Essential oil yield was det
ermined as a function of time. Yield data and physical considerations based
on the botanical structure of pennyroyal leaves were used to screen the po
ssible mass transfer mechanisms. Two mathematical models were constructed,
based on the numerical integration of differential mass balances written al
ong the extraction bed. They take into account the desorption of essential
oil located near the leaf surface and the mass transfer resistance to the e
xtraction of the part of essential oil contained in the internal part of th
e vegetable structure. Axial dispersion was also taken into account. Yield
curves for all particle sizes and CO2 how rates were fairly well fitted usi
ng the internal mass transfer coefficient K-i as the only adjustable parame
ter of the model. The best fit value was K-i = 1.4 x 10(-7) m/s. Once the m
odel was validated on the experimental data, simulations were performed for
(a) different partitions of essential oil between the surface and internal
cells of leaves, and (b) a larger range of CO2 flow rates. Simulation resu
lts can be applied to other vegetable species and to determine the performa
nce of this process on a larger scale plant. (C) 2000 Elsevier Science Ltd.
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