Antiferroelectricity in achiral mesogenic mixtures of organic materials

Citation
Eas. Bustamante et al., Antiferroelectricity in achiral mesogenic mixtures of organic materials, CHEM P LETT, 322(1-2), 2000, pp. 45-50
Citations number
6
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
322
Issue
1-2
Year of publication
2000
Pages
45 - 50
Database
ISI
SICI code
0009-2614(20000512)322:1-2<45:AIAMMO>2.0.ZU;2-B
Abstract
To clarify the mechanism involved in the appearance of antiferroelectric pr operties in mixtures of polymers containing achiral mesogenic side chains a nd their monomers, X-ray investigation was carried out in pyroelectrically active samples. The thermal stability of such systems is also reported. The X-ray investigation shows that in highly concentrated mixtures of monomer in polymer, a segregation of the excess of monomer from an optimized ratio (33% monomer/polymer) occurs. (C) 2000 Elsevier Science B.V. All rights res erved,