Silica-coated titania and zirconia colloids for subsurface transport fieldexperiments

Silica-coated titania (TiO2) and zirconia (ZrO2) colloids were synthesized in two sizes to provide easily traced mineral colloids for subsurface trans port experiments. Electrophoretic mobility measurements showed that coating with silica imparted surface properties similar to pure silica to the tita nia and zirconia colloids. Measurements of steady electrophoretic mobility and size (by dynamic light scattering) over a 90-day period showed that the silica-coated colloids were stable to aggregation and loss of coating. A n atural gradient field experiment conducted in an iron oxide-coated sand and gravel aquifer also showed that the surface properties of the silica-coate d colloids were similar. Colloid transport was traced at mu g L-1 concentra tions by inductively coupled plasma-atomic emission spectroscopy measuremen t of Ti and Zr in acidified samples.