Thermal condensation of trinuclear lanthanide butoxides. Molecular structure of La-5 (mu(5)-O) (mu(3)-(OBu)-Bu-t)(4)(mu-(OBu)-Bu-t)(4)((OBu)-Bu-t)(5)

Authors
Daniele, S Hubert-Pfalzgraf, LG Hitchcock, PB Lappert, MF
Citation
S. Daniele et al., Thermal condensation of trinuclear lanthanide butoxides. Molecular structure of La-5 (mu(5)-O) (mu(3)-(OBu)-Bu-t)(4)(mu-(OBu)-Bu-t)(4)((OBu)-Bu-t)(5), INORG CH C, 3(5), 2000, pp. 218-220
Citations number
27
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
5
Year of publication
2000
Pages
218 - 220
Database
ISI
SICI code
1387-7003(200005)3:5<218:TCOTLB>2.0.ZU;2-B
Abstract
Refluxing of Ln(3)((OBu)-Bu-t)(9)((BuOH)-Bu-t)(2) (Ln=La, Nd, Yb) in toluen e led to Ln(5)O((OBu)-Bu-t)(13) which was characterised by X-ray diffractio n in the case of lanthanum. Aggregates of higher nuclearity were obtained i n similar conditions for yttrium and praseodymium. (C) 2000 Elsevier Scienc e S.A. All rights reserved.