Synthesis and copolymerization of rhodium(I) and palladium(II) complexes with the deprotonated form of 2-(acetoacetoxy)ethyl methacrylate

Authors
Dell'Anna, MM Mastrorilli, P Rizzuti, A Suranna, GP Nobile, CF
Citation
Mm. Dell'Anna et al., Synthesis and copolymerization of rhodium(I) and palladium(II) complexes with the deprotonated form of 2-(acetoacetoxy)ethyl methacrylate, INORG CHIM, 304(1), 2000, pp. 21-25
Citations number
28
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
304
Issue
1
Year of publication
2000
Pages
21 - 25
Database
ISI
SICI code
0020-1693(20000615)304:1<21:SACORA>2.0.ZU;2-D
Abstract
The reactions of [(cod)RhCl](2) (cod = 1,5-cyclooctadiene) and Na2PdCl4 wit h the anion of 2-(acetoacetoxy)ethyl methacrylate (AAEMA(-)) afforded (cod) Rh(AAEMA) (1) and Pd(AAEMA)(2) (2). Thermal copolymerization of 1 and 2 wit h suitable comonomers and cross-linkers yielded insoluble resins that have been characterised by elemental analyses, IR, UV-Vis, XPS and SEM technique s and successfully used in the hydrogenation of 1-heptene under mild condit ions. (C) 2000 Elsevier Science S.A. All rights reserved.