Copper-mediated oxygenation of flavonolate in the presence of a tridentateN-ligand. Synthesis and crystal structures of [Cu(fla)(idpaH)]ClO4 and [Cu(idpaH)(O-bs)]ClO4, [fla = flavonolate, idpaH=3,3 '-iminobis(N,N-dimethylpropylamine), O-bs = O-benzoylsalicylate]

Authors
Balogh-Hergovich, E Kaizer, J Speier, G Huttner, G Zsolnai, L
Citation
E. Balogh-hergovich et al., Copper-mediated oxygenation of flavonolate in the presence of a tridentateN-ligand. Synthesis and crystal structures of [Cu(fla)(idpaH)]ClO4 and [Cu(idpaH)(O-bs)]ClO4, [fla = flavonolate, idpaH=3,3 '-iminobis(N,N-dimethylpropylamine), O-bs = O-benzoylsalicylate], INORG CHIM, 304(1), 2000, pp. 72-77
Citations number
32
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
304
Issue
1
Year of publication
2000
Pages
72 - 77
Database
ISI
SICI code
0020-1693(20000615)304:1<72:COOFIT>2.0.ZU;2-C
Abstract
The complexes [Cu(fla)(idpaH)] ClO4 (4) and [Cu(idpaH)(O-bs)] ClO4 (5) (fla = flavonolate, idpaH = 3,3'-iminobis(N, N-dimethylpropylamine), O-bs = O-b enzoylsalicylate) have been synthesised and characterised. Complex 5 can be obtained also by the oxygenation of 4 and concomitant CO release. The stru ctures of the compounds have been determined by X-ray diffraction. Complex 4 exhibits distorted trigonal-bipyramidal geometry around the copper(II) io n while complex 5 is distorted square-pyramidal. (C) 2000 Elsevier Science S.A. All rights reserved.