Structure of trans-diisothiocyanato(ethoxo)oxo-bis(triphenylphosphine)rhenium(V) complex

Authors
Battistuzzi, R Saladini, M
Citation
R. Battistuzzi et M. Saladini, Structure of trans-diisothiocyanato(ethoxo)oxo-bis(triphenylphosphine)rhenium(V) complex, INORG CHIM, 304(1), 2000, pp. 114-117
Citations number
36
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
304
Issue
1
Year of publication
2000
Pages
114 - 117
Database
ISI
SICI code
0020-1693(20000615)304:1<114:SOT>2.0.ZU;2-6
Abstract
The title compound consists of [ReO(NCS)(2)(OEt)(PPh3)(2)] units in which t he rhenium(V) center shows a slightly distorted octahedral coordination. Th e two N-coordinated NCS- groups are trans to each other, as the Re=O and th e Re-Oft units. The Re=O and Re-OEt bond lengths [1.682(10) and 1.871(10) A ngstrom, respectively] and the geometry about the ethoxide oxygen atom indi cate that in both cases M-O ligation has a considerable degree of multiple bond. (C) 2000 Elsevier Science S.A. All rights reserved.