Synthesis and crystal structure of an imidochromium(V) complex with a thioether macrocyclic ligand

Authors
Leung, WH Wu, MC Wong, TKT Wong, WT
Citation
Wh. Leung et al., Synthesis and crystal structure of an imidochromium(V) complex with a thioether macrocyclic ligand, INORG CHIM, 304(1), 2000, pp. 134-136
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
304
Issue
1
Year of publication
2000
Pages
134 - 136
Database
ISI
SICI code
0020-1693(20000615)304:1<134:SACSOA>2.0.ZU;2-X
Abstract
Reaction of [Cr(NBut)Cl-3(dme)] (dme = 1,2-dimethoxyethane) with 1,4,7-trit hiacyclononane ([9]aneS(3)) followed by treatment with Ag(CF3SO3) leads to the isolation of [Cr((NBu)-Bu-t)([9]aneS(3))Cl-2(CF3SO3), which has been ch aracterized by X-ray crystallography. The Cr-N, average Cr-S, and average C r-Cl distances are 1.640(4), 2.431, and 2.273 Angstrom, respectively; the C r-N-C angle being 173.2(4)degrees. (C) 2000 Elsevier Science S.A. All right s reserved.