Mono- and dinuclear Ni(II) complexes with N3O Schiff base ligands. Crystalstructure of [Ni(AEPyz)]ClO4 (HAEPyz derived from 7-amino-4-methyl-5-aza-3-hepten-2-one and 2-acetylpyrazine)

Authors
Fernandez-Garcia, MI Fernandez-Fernandez, B Fondo, M Garcia-Deibe, AM Gomez-Forneas, E Bermejo, MR Sanmartin, J Gonzalez, AM
Citation
Mi. Fernandez-garcia et al., Mono- and dinuclear Ni(II) complexes with N3O Schiff base ligands. Crystalstructure of [Ni(AEPyz)]ClO4 (HAEPyz derived from 7-amino-4-methyl-5-aza-3-hepten-2-one and 2-acetylpyrazine), INORG CHIM, 304(1), 2000, pp. 144-149
Citations number
29
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
304
Issue
1
Year of publication
2000
Pages
144 - 149
Database
ISI
SICI code
0020-1693(20000615)304:1<144:MADNCW>2.0.ZU;2-X
Abstract
wMono- and dinuclear nickel(II) complexes with N3O asymmetrical Schiff base s have been prepared and characterised. The ligands used here were obtained by condensation of the amine 7-amino-4-methyl-5-aza-3-hepten-2-one (HAE) a nd 4(5)-imidazolecarboxaldehyde or 2-acetylpyrazine, to yield the isolated Schiff bases H(2)AE4(5)Im and HAEPyz, respectively. Physicochemical data (m ean) indicate that all the complexes are quasi square planar. The X-ray cry stal structure of [Ni(AEPyz)]ClO4 is reported, whose NiN3O cromophore is re markably square planar. (C) 2000 Elsevier Science S.A. All rights reserved.