The results of an investigation of afterpulses arising in a proportional co
unter due to the photoeffect on the cathode are presented. It was found tha
t, as the gas amplification changes, the amplitude of afterpulses becomes p
roportional to the square amplitude of the primary pulse, and that the coef
ficient of proportionality can serve as a criterion for comparing the emiss
ion properties of cathodes made of various materials. Such a comparison was
performed for cathodes of stainless steel, copper, beryllium, and aluminum
alloys. It was found that phosphatizing of aluminum produces a coating, wh
ich essentially reduces the photoeffect on the cathode. Unlike anodic oxida
tion, a phosphate layer possesses sufficient conductivity that prevents spo
ntaneous discharges in a counter caused by accumulation of electrical charg
es followed by an electrical breakdown of the coating layer.