In organometallic vapor phase epitaxy, changes in growth conditions can be
used to modulate the extent of CuPt ordering and, hence, the band gap energ
y of GaInP. One method is to add Te during growth. An increase in the band
gap energy of 0.1 eV due to a decrease in ordering has been obtained by inc
reasing the input pressure of diethyltelluride from 0 to 8x10(-6) Torr, whi
ch corresponds to a doping concentration of 6x10(17) cm(-3). This simple pr
ocedure offers an attractive method to grow quantum wells (QWs) and superla
ttices, which are useful for band gap engineering, by modulating the input
pressure of the Te precursor. Various heterostructures with abrupt interfac
es were successfully grown with interruptions at the interfaces between the
Te-doped and undoped GaInP layers. QWs as thin as 10 nm can be clearly see
n from transmission electron microscope images. (C) 2000 American Institute
of Physics. [S0021- 8979(00)07411-9].