Radiation induced grafting of acrylic acid onto polyethylene film was inves
tigated. The grafted films rapidly adsorbed Cu2+, Cd2+, Th4+, and UO22 ions
in high efficiency. The carboxylic acid groups on AAc-grafted PE film acte
d as a chelating site for the selected metal ions. Complex formation of met
al ions and carboxylic acid group on PE film were investigated by IR, UV/VI
S and x-ray photoelectrons spectroscopy (XPS). Electrical conductivity and
thermal properties of the graft copolymer-metal complexes onto PE film were
also investigated. The application of such prepared graft copolymer-metal
complexes in the field of semiconductor may be interest. (C) 2000 John Wile
y & Sons, Inc.