F. Qi et al., Structural relaxation of the fragile glass-former propylene carbonate studied by nuclear magnetic resonance, J CHEM PHYS, 112(21), 2000, pp. 9455-9462
Proton, deuteron, and carbon NMR methods were applied to study various isot
opic species of supercooled and glassy propylene carbonate. The molecular d
iffusion was investigated via static field gradient diffusometry and yielde
d evidence for a particularly pronounced enhancement of the translational o
ver the reorientational dynamics. The latter was monitored using measuremen
ts of spin-lattice relaxation times and of two-time stimulated echoes. The
sin-sin correlation functions exhibited a pronounced dependence on the evol
ution times. From these results it is concluded that the geometry of molecu
lar reorientation can be described as a superposition of moderately small j
ump angles (about 30 degrees) and a quasi-diffusive component which is resp
onsible for about one-third of the total angular displacement. Finally, fou
r-time stimulated echoes confirmed that the nonexponential relaxation in pr
opylene carbonate is dynamically heterogeneous in nature. (C) 2000 American
Institute of Physics. [S0021-9606(00)50821-6].