The direct interpretability of atomic resolution Z-contrast images obtained
from a scanning transmission electron microscope (STEM) makes this imaging
technique particularly powerful for the analysis of interfaces and defects
in semiconductor materials and devices. In this paper, the principles of t
he technique are outlined and representative examples of its use are presen
ted. In particular, we show the use of Z-contrast imaging to determine the
polarity of a CdTe film grown on a Si substrate, the atomic structures of s
tacking faults and threading dislocation cores in GaN, and the atomistic st
ructure of an ohmic metal/semiconductor contact of Au/GaAs.