Polycrystalline CoSn alloy thin films have been successfully prepared by lo
w-pressure chemical vapor deposition from two single-source organometallic
precursors containing Co-Sn bonds, Me3SnCo(CO)(4) at 250-300 degrees C and
Ph3SnCo(CO)(4) at 300-400 degrees C. Deposition rates were 250-660 Angstrom
min(-1). Deposited films were characterized by scanning electron microscop
ic, energy dispersive spectroscopic, atomic absorption spectroscopic, X-ray
diffraction, and Auger electron spectroscopic analyses. Co and Sn elements
are evenly distributed in the films. The films are composed of the CoSn ph
ase with a minor constituent of alpha-Co3Sn2.