The binary system AgNO3-LiNO3 - Phase diagram and thermodynamic propertiesof mixed ligands

Authors
Hichri, M Zamali, H Jemal, M
Citation
M. Hichri et al., The binary system AgNO3-LiNO3 - Phase diagram and thermodynamic propertiesof mixed ligands, J THERM ANA, 60(2), 2000, pp. 453-461
Citations number
25
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN journal
13886150 → ACNP
Volume
60
Issue
2
Year of publication
2000
Pages
453 - 461
Database
ISI
SICI code
1388-6150(2000)60:2<453:TBSA-P>2.0.ZU;2-9
Abstract
To study the coherence of thermodynamic data of the AgNO3-LiNO3-RbNO3 terna ry system, phase diagram of the binary system AgNO3-LiNO3 has been obtained between 303 and 550 K by direct and differential thermal analysis techniqu e. This system is characterized by an eutectic point (25% mol. LiNO3, 445-1 K) and a plateau due to the solid-solid transition in AgNO3 at 434-1 K. In the solid state the solubility of each component in the other seems to be nil or negligible (no more than a few percents). Using other thermodynamic data, the excess properties of the binary liquid (AgNO3- LiNO3) were calcul ated at 623 K.