S. Nakahata et al., ELECTRON-SPIN-RESONANCE ANALYSIS OF LATTICE-DEFECTS IN POLYCRYSTALLINE ALUMINUM NITRIDE, Journal of the American Ceramic Society, 80(6), 1997, pp. 1612-1614
Electron spin resonance was used in the present study to detect lattic
e defects in an aluminum nitride lattice, The ESR spectra were obtaine
d from pola crystalline AIN with various thermal conductivities. Measu
rement of the AIN g values clearly indicated that the obtained ESR sig
nals arose from electrons trapped by nitrogen vacancies, The ESR study
revealed that thermal conductivity increases with an increase in the
number of electrons trapped by nitrogen vacancies. The explanation for
that phenomenon is that the thermal conductivity of AIN increases wit
h a decreasing concentration of oxygen impurities incorporated into th
e UN lattice. and the concentration of nitrogen vacancies changes inve
rsely with the concentration of oxygen impurities.