HIGHLY ERYTHRO-SELECTIVE 2-CYCLOHEXENYLATION OF ALDEHYDES PROMOTED BYACTIVE METAL BISMUTH FROM NABH4 AND BICL3

Authors
REN PD SHAO D DONG TW
Citation
Pd. Ren et al., HIGHLY ERYTHRO-SELECTIVE 2-CYCLOHEXENYLATION OF ALDEHYDES PROMOTED BYACTIVE METAL BISMUTH FROM NABH4 AND BICL3, Synthetic communications, 27(15), 1997, pp. 2569-2576
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
27
Issue
15
Year of publication
1997
Pages
2569 - 2576
Database
ISI
SICI code
0039-7911(1997)27:15<2569:HE2OAP>2.0.ZU;2-Q
Abstract
In the presence of Bu4NBr in DMF solution, the reaction of 3-bromocycl ohexene and active metal bismuth from NaBH4 and BiCl3 with aromatic an d aliphatic aldehydes provides excellent erythro-selective products.