Imposing curvature on a polyarene by intramolecular palladium-catalyzed arylation reactions: A simple synthesis of dibenzo[a,g]corannulene

Authors
Reisch, HA Bratcher, MS Scott, LT
Citation
Ha. Reisch et al., Imposing curvature on a polyarene by intramolecular palladium-catalyzed arylation reactions: A simple synthesis of dibenzo[a,g]corannulene, ORG LETT, 2(10), 2000, pp. 1427-1430
Citations number
37
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
10
Year of publication
2000
Pages
1427 - 1430
Database
ISI
SICI code
1523-7060(20000518)2:10<1427:ICOAPB>2.0.ZU;2-9
Abstract
[GRAPHICS] Palladium catalysis has been found to offer an effective solution phase alt ernative to gas phase flash vacuum pyrolysis as a method for converting the planar ring system of 7,10-di(2-bromophenyl)fluoranthene (4) to that of th e C28H14 bowl-shaped fullerene fragment dibenzo[a,g]corannulene (5).