Synthesis and structure of group 4 and 5 metal complexes with an ancillarysterically demanding diamido ligand

Authors
Lorber, C Donnadieu, B Choukroun, R
Citation
C. Lorber et al., Synthesis and structure of group 4 and 5 metal complexes with an ancillarysterically demanding diamido ligand, ORGANOMETAL, 19(10), 2000, pp. 1963-1966
Citations number
33
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
10
Year of publication
2000
Pages
1963 - 1966
Database
ISI
SICI code
0276-7333(20000515)19:10<1963:SASOG4>2.0.ZU;2-R
Abstract
Reaction of tetrachlorides of group 4 and 5 transition metals with the chel ating diamide [Me2C(CH2N(Li)((SiBuPh2)-Ph-t))(2)] (LLi2) leads to LMCl2 (M = Ti, Zr, Hf V) complexes, which were characterized by X-ray diffraction. T he reactivity of LMCl2 toward ethylene polymerization was tested with MAO a s cocatalyst.