Certain inflation models undergo pre-heating, in which inflaton oscillation
s can drive parametric resonance instabilities. We discuss several phenomen
a stemming from such instabilities, especially in weak-scale models; generi
cally, these involve energizing a resonant system so that it can evade tunn
eling by crossing barriers classically. One possibility is a spontaneous ch
ange of phase from a lower-energy vacuum state to one of higher energy, as
exemplified by an asymmetric double-well potential with different masses in
each well. If the lower well is in resonance with oscillations of the pote
ntial, a system can be driven resonantly to the upper well and stay there (
except for tunneling) if the upper well is not resonant. Another example oc
curs in hybrid inflation models where the Higgs field is resonant; the Higg
s oscillations can be transferred to electroweak (EW) gauge potentials, lea
ding to rapid transitions over sphaleron barriers and consequent B + L viol
ation. Given an appropriate CP-violating seed, we find that preheating can
drive a time-varying condensate of Chern-Simons number over large spatial s
cales; this condensate evolves by oscillation as well as decay into modes w
ith shorter spatial gradients, eventually ending up as a condensate of spha
lerons. We study these examples numerically and to some extent analytically
. The emphasis in the present paper is on the generic mechanisms, and not o
n specific preheating models; these will be discussed in a later paper.