Steric interaction of an incoming particle with grafted rods: Exact solutions and unusual force profiles

Citation
Icb. Miller et Drm. Williams, Steric interaction of an incoming particle with grafted rods: Exact solutions and unusual force profiles, PHYS REV E, 61(5), 2000, pp. R4706-R4709
Citations number
15
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW E
ISSN journal
1063651X → ACNP
Volume
61
Issue
5
Year of publication
2000
Part
A
Pages
R4706 - R4709
Database
ISI
SICI code
1063-651X(200005)61:5<R4706:SIOAIP>2.0.ZU;2-1
Abstract
We examine the problem of a grafted rod or rods compressed by a sphere, con centrating on the steric force exerted by the rods on the sphere. We show t hat this problem can be solved exactly to yield simple and nontrivial expre ssions for the repulsive force. In particular, there are several different regimes and in some of these the force exhibits surprising maxima and minim a as a function of compression. This has applications to systems of stiff g rafted polymers, particularly biopolymers. One experimental realization of our system might be a rod-coil diblock copolymer with the coil grafted to a solid surface.