A. Carati et L. Galgani, Analog of Planck's formula and effective temperature in classical statistical mechanics far from equilibrium, PHYS REV E, 61(5), 2000, pp. 4791-4794
We study the statistical mechanics very far from equilibrium for a classica
l system of harmonic oscillators colliding with point particles (mimicking
a heat reservoir), for negligible initial energies of the oscillators. It i
s known that for high frequencies the times of relaxation to equilibrium ar
e extremely long, so that one meets with situations of quasiequilibrium ver
y far from equilibrium similar to those of glassy systems. Using recent res
ults from the theory of dynamical systems, we deduce a functional relation
between energy variance and mean energy that was introduced by Einstein phe
nomenologically in connection with Planck's formula. It is then discussed h
ow this leads to an analog of Planck's formula. This requires using Einstei
n's relation between specific heat and energy variance to define an effecti
ve temperature in a context of quasiequilibrium far from equilibrium, as is
familiar for glassy systems.