The metastable microstructures in two rapidly solidified Ni rich Ti-Ni
alloys are studied. A first report of the presence of a cubic phase w
ith three times the lattice parameter of B2-TiNi in melt spun Ti40Ni60
alloy is presented. This phase has precipitated from the massively so
lidified BZ-TiNi. We also report the formation of a faulted structure
(A), polytypic to TiNi3 along with TiNi3 in melt spun Ti30Ni70 alloy.
It is argued that this structure is stabilised due to a specific valen
ce electron by atom ratio.