Seven novel saponins were isolated from a bark extract of Quillaja saponari
a Molina, the compounds were characterized, using mainly NMR spectroscopy,
mass spectrometry and chemical methods, as quillaic acid substituted at C-3
with oligosaccharides consisting of various compositions of D-glucuronic a
cid D-galactose, D-xylose, and L-rhamnose and at C-28 with complex oligosac
charide structures consisting of various compositions of D-xylose, L-rhamno
se, D-apiose and a branched 4-O-acetyl-D-fucose residue. (C) 2000 Elsevier
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