Synthesis and properties of polycyclic aliphatic copper, silver, and mercury acetylides

Authors
Dikusar, EA Koval'skaya, SS Vashkevich, EV Kozlov, NG Potkin, VI Moiseichuk, KL
Citation
Ea. Dikusar et al., Synthesis and properties of polycyclic aliphatic copper, silver, and mercury acetylides, RUSS J G CH, 69(11), 1999, pp. 1732-1735
Citations number
12
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
11
Year of publication
1999
Pages
1732 - 1735
Database
ISI
SICI code
1070-3632(199911)69:11<1732:SAPOPA>2.0.ZU;2-W
Abstract
1-Ethynyladamantane, (+/-)-2-endo-ethynyl-1,7,7-trimethylbicyclo[2.2.1]hept an-2-exo-ol, 2-exo-ethynyl-5,5,6-trimethylbicyclo[2.2.1]heptan-2-endo-ol, a nd 1-octadecyne were reacted with CuCl, [Ag(NH3)(2)] . NO3, and K-2[HgI4] t o prepare previously unknown copper, silver, and mercury acetylides. The si lver acetylides were shown to smoothly react with iodine to give iodoethyny l derivatives.