Synthesis of alpha-chloronitro compounds

Citation
Ik. Moiseev et al., Synthesis of alpha-chloronitro compounds, RUSS J G CH, 69(11), 1999, pp. 1777-1778
Citations number
17
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
11
Year of publication
1999
Pages
1777 - 1778
Database
ISI
SICI code
1070-3632(199911)69:11<1777:SOAC>2.0.ZU;2-5
Abstract
Treatment of acetone oxime, cyclohexanone oxime, bicyclo[3.3,1]nonane-2,6-d ione dioxime, 2-adamantanone oxime, and 1,3-dicarboxyadamantane-2,6-dione d ioxime with a mixture of hydrochloric acid and 30% hydrogen peroxide gave 2 -chloro-2-nitropropane, 1-chloro-1-nitrocyclohexane, 2,6-dichloro-2,6-dinit robicyclo[3.3. 1]nonane, 2-chloro-2-nitroadamantane, and 2,6-dichloro-2,6-d initroadamantane-1,3-dicarboxylic acid.