Synthesis of certain 1,3-disubstituted 5-(omega-mercaptoalkyl)isocyanurates

Citation
Mm. Shulaeva et al., Synthesis of certain 1,3-disubstituted 5-(omega-mercaptoalkyl)isocyanurates, RUSS J G CH, 69(11), 1999, pp. 1827-1831
Citations number
19
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
11
Year of publication
1999
Pages
1827 - 1831
Database
ISI
SICI code
1070-3632(199911)69:11<1827:SOC15>2.0.ZU;2-8
Abstract
1,3-dimethy1 and 1,3-diallyl 5-(omega-bromoalkyl) isocyanurates were reacte d with thiourea to obtain the corresponding isothiuronium bromides. Hydroly sis of the salts gave the corresponding 1,3-disubstituted 5-(omega-mercapto alkyl) isocyanurates. 1,3-Diallyl 5-(omega-mercaptoalkyl) isocyanurates und ergo intermolecular addition of the mercapto groups to the allyl double bon ds to yield polymers insoluble in organic solvents.