S. Stemmer et al., Characterization of oxygen-deficient SrCoO3-delta by electron energy-loss spectroscopy and Z-contrast imaging, SOL ST ION, 130(1-2), 2000, pp. 71-80
Atomic resolution Z-contrast imaging and electron energy-loss spectroscopy
(EELS) were used to study the defect structure of oxygen deficient strontiu
m cobaltite (SrCoO3-delta) after repeated oxidation/reduction cycles at ele
vated temperatures. Ordered microdomains were found in the reduced sample.
Z-contrast imaging showed ordering in alternate CoO2 planes, characteristic
for a brownmillerite-type vacancy ordered structure. EELS showed that the
average valence state of cobalt had decreased after testing. In the tested
sample, cobalt was found in + 3 and + 2 valence states, respectively. In ad
dition, cobalt oxide precipitates were found at grain boundaries and in tri
ple pockets in this sample, indicating a cobalt deficiency of the grains. T
he mechanisms for the formation of the observed microstructure are discusse
d. (C) 2000 Elsevier Science B.V. All rights reserved.