A modified Suzuki reaction of 1,1-dibromo-1-alkenes

Authors
Shen, W
Citation
W. Shen, A modified Suzuki reaction of 1,1-dibromo-1-alkenes, SYNLETT, (5), 2000, pp. 737-739
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
5
Year of publication
2000
Pages
737 - 739
Database
ISI
SICI code
0936-5214(200005):5<737:AMSRO1>2.0.ZU;2-W
Abstract
The (E)-bromides in 1,1-dibromo-1-alkenes were stereoselectively coupled wi th aryl- or alkenylboronic acids to give the corresponding (Z)-1-Aryl(alken yl)-1-bromo-1-alkenes. Tris(2-furyl)phosphine (TFP) was used as the ligand to palladium, and the combination of 1,4-dioxane and aqueous sodium carbona te produced the best results.