Synthesis of functionalized mono-, di-, tri-, and tetraphosphines: Attempted application to prepare hyperbranched polymers and dendrimers built with phosphines at each branching point
V. Huc et al., Synthesis of functionalized mono-, di-, tri-, and tetraphosphines: Attempted application to prepare hyperbranched polymers and dendrimers built with phosphines at each branching point, SYNTHESIS-S, (5), 2000, pp. 726-730
The synthesis of several functionalized mono-, di-, tri-, and tetraphosphin
es is described. These compounds are used for the attempted preparation of
hyperbranched polymers and dendrimers possessing free phosphino groups at e
ach branching point within the structure. Theses attempts were not fully su
ccessful, but several phosphaacetylenic derivatives have been isolated.