Facile synthesis of steroidal phenyl ketones via homogeneous catalytic carbonylation

Authors
Skoda-Foldes, R Szekvolgyi, Z Kollar, L Berente, Z Horvath, J Tuba, Z
Citation
R. Skoda-foldes et al., Facile synthesis of steroidal phenyl ketones via homogeneous catalytic carbonylation, TETRAHEDRON, 56(21), 2000, pp. 3415-3418
Citations number
18
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
56
Issue
21
Year of publication
2000
Pages
3415 - 3418
Database
ISI
SICI code
0040-4020(20000519)56:21<3415:FSOSPK>2.0.ZU;2-R
Abstract
Steroidal phenyl ketones were synthesised in high yields by palladium-catal ysed carbonylation reactions of 17-iodo-androst-16-ene derivatives in the p resence of NaBPh4 under mild reaction conditions. Alkenyl bromides or enol triflates gave lower yields in the same reaction. (C) 2000 Elsevier Science Ltd. All rights reserved.