Catalytic and supported Barton-McCombie deoxygenation of secondary alcohols: a clean reaction

Authors
Boussaguet, P Delmond, B Dumartin, G Pereyre, M
Citation
P. Boussaguet et al., Catalytic and supported Barton-McCombie deoxygenation of secondary alcohols: a clean reaction, TETRAHEDR L, 41(18), 2000, pp. 3377-3380
Citations number
11
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
18
Year of publication
2000
Pages
3377 - 3380
Database
ISI
SICI code
0040-4039(20000429)41:18<3377:CASBDO>2.0.ZU;2-G
Abstract
Secondary alcohols were deoxygenated using a new version of the Barton-McCo mbie process involving a catalytic amount of supported tin hydride in the p resence of trimethoxysilane. The products are then easily separated from th e catalyst by a simple filtration avoiding pollution by toxic tin by-produc ts. (C) 2000 Elsevier Science Ltd. All rights reserved.