A highly chemoselective and diastereoselective trifluoromethane sulfonic acid catalyzed addition of allyltributylstannanes to a steroidal aldehyde inaqueous media

Authors
Loh, TP Xu, J Hu, QY Vittal, JJ
Citation
Tp. Loh et al., A highly chemoselective and diastereoselective trifluoromethane sulfonic acid catalyzed addition of allyltributylstannanes to a steroidal aldehyde inaqueous media, TETRAHEDR-A, 11(7), 2000, pp. 1565-1569
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
11
Issue
7
Year of publication
2000
Pages
1565 - 1569
Database
ISI
SICI code
0957-4166(20000420)11:7<1565:AHCADT>2.0.ZU;2-M
Abstract
Trifluoromethane sulfonic acid catalyzes the addition of allylic tributylst annanes to steroidal aldehyde 1 ill aqueous media to give the corresponding homoallylic alcohols in high yields and high diastereoselectivities. (C) 2 000 Elsevier Science Ltd. All rights reserved.