THE REACTIVITY OF CALIX[4]RESORCINOLARENE ANIONS TOWARDS P-NITROPHENYL ESTERS OF TETRACOORDINATED PHOSPHORUS-ACIDS

Authors
RYZHKINA IS KUDRYAVTSEVA LA KAZAKOVA EK BURILOV AR KONOVALOV AI
Citation
Is. Ryzhkina et al., THE REACTIVITY OF CALIX[4]RESORCINOLARENE ANIONS TOWARDS P-NITROPHENYL ESTERS OF TETRACOORDINATED PHOSPHORUS-ACIDS, Mendeleev communications, (3), 1997, pp. 88-90
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
3
Year of publication
1997
Pages
88 - 90
Database
ISI
SICI code
0959-9436(1997):3<88:TROCAT>2.0.ZU;2-4
Abstract
The results of a kinetic study have shown that the reactivity of monom eric forms of amphiphilic tetra-([H4L](4-)) and octa-([L](8-)) anions of calix[4]resorcinolarenes (H8L) towards p-nitrophenyl esters of tetr acoordinated phosphorus acids in aqueous dimethylformamide (50 vol.% o f DMF) is determined by the nucleophilic centres of the anions, wherea s an increase in the concentration of H8L inhibits the process, which is due to the formation of aggregates.