In recent years the discovery of the starch fraction called resistant
starch (RS) has lead to numerous investigations. The nature of this fr
action is very heterogeneous, and it comprises different types of resi
stant starches. From a technological point of view, RS type III or ret
rograded starch is the most important fraction. This resistant starch
is formed after heating and cooling processes which therefore may occu
r in numerous fresh foods and foodstuffs. This brief review describes
the gelatinization and retrogradation, which occur during heating and
cooling, involved in the formation of resistant starch. The influence
on RS formation of technological processes used in the manufacture of
cereals has been studied as well as the influence of certain treatment
s used in legumes. In addition, the interactions between starch and nu
trients such as proteins, lipids and sugars have also been studied. Re
cently, a high pressure autoclave has been used in a gelatinization sy
stem, which allows a better technological control and an increase in R
S yields in comparison to conventional systems.