Complex wastewater is defined in this context as containing significant lev
els of fats, proteins or particulates. High-rate anaerobic treatment of com
plex wastewater is becoming more popular due to economic and environmental
advantages. However, treatment is complicated because of the high levels of
solids and fats and lack of knowledge of degradation mechanisms. This pape
r is the first part of a study of a structural model describing degradation
of complex wastewater. A structural anaerobic model is developed which ext
ends previous research, of which the most recent described the anaerobic de
gradation of soluble protein (Ramsay, I.R., 1997. Modelling and Control of
High-Rate Anaerobic Wastewater Treatment Systems. Ph.D. Thesis, Department
of Chemical Engineering, The University of Queensland, Brisbane, Australia)
. This study incorporates hydrolysis of particulates and long chain fatty a
cid (LCFA) beta-oxidation. A set of physico-chemical equations describes ga
s transfer and ionic reactions and structured biochemical equations describ
e biological and enzymatic reactions. A generic parameter estimation method
ology for application to full-scale systems is also proposed. (C) 2000 Else
vier Science Ltd. All rights reserved.