Persistent carbenes containing acetylenes: 4,5-dialkynylimidazol-2-ylidene

Citation
R. Faust et B. Gobelt, Persistent carbenes containing acetylenes: 4,5-dialkynylimidazol-2-ylidene, CHEM COMMUN, (11), 2000, pp. 919-920
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
11
Year of publication
2000
Pages
919 - 920
Database
ISI
SICI code
1359-7345(2000):11<919:PCCA4>2.0.ZU;2-V
Abstract
A nucleophilic imidazole carbene featuring acetylene substituents in the 4- and 5-positions is prepared in three steps from dialkynyl diimines and is characterised by low temperature NMR spectroscopy and trapping reactions wi th MeI, CS2 and HgCl2.