Citation
Sv. Kryatov et al., A dinuclear iron(III) complex with a bridging urea anion: implications forthe urease mechanism, CHEM COMMUN, (11), 2000, pp. 921-922
Citations number
23
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345
→ ACNP
Issue
11
Year of publication
2000
Pages
921 - 922
Database
ISI
SICI code
1359-7345(2000):11<921:ADICWA>2.0.ZU;2-V
Abstract
A novel complex [Fe-2(III)(mu-O){mu-OC(NH2)NH}(tpa)(2)](ClO4)(3) [tpa = tri
s(2-pyridylmethyl)amine] has been synthesized and fully characterized; its
formation from urea and the [Fe-2(III)(mu-O)(tpa)(2)(OH)(H2O)](3+) precurso
r in aqueous acetonitrile is a reversible multistep process.