Novel hepta-coordinated molybdenum(II) and tungsten(II) carbene complexes by oxidative decarbonylation of Mo(0) and W(0) carbene complexes

Authors
Jaeger, M Stumpf, R Troll, C Fischer, H
Citation
M. Jaeger et al., Novel hepta-coordinated molybdenum(II) and tungsten(II) carbene complexes by oxidative decarbonylation of Mo(0) and W(0) carbene complexes, CHEM COMMUN, (11), 2000, pp. 931-932
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
11
Year of publication
2000
Pages
931 - 932
Database
ISI
SICI code
1359-7345(2000):11<931:NHMATC>2.0.ZU;2-2
Abstract
C,O-Chelated tetracarbonyl[o-methoxyphenyl(methoxy)-carbene] complexes of m olybdenum(0) and tungsten(0) react with tin tetrahalides SnX4 (X = Cl, Br, I) by oxidative decarbonylation and incorporation of two halides to form no vel chelated hepta-coordinated Fischer-type tricarbonyl-(bishalogeno)carben e molybdenum(II) and tungsten(II) complexes.