The arched four-rung ladder structure of the unsolvated dilithium salt of N,N'-bis(trimethylsilyl)-2-aminobenzylamine, and its structural deformationon THF complexation

Authors
Gauvin, RM Kyritsakas, N Fischer, J Kress, J
Citation
Rm. Gauvin et al., The arched four-rung ladder structure of the unsolvated dilithium salt of N,N'-bis(trimethylsilyl)-2-aminobenzylamine, and its structural deformationon THF complexation, CHEM COMMUN, (11), 2000, pp. 965-966
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
11
Year of publication
2000
Pages
965 - 966
Database
ISI
SICI code
1359-7345(2000):11<965:TAFLSO>2.0.ZU;2-H
Abstract
The X-ray crystal structures of 2-Li(SiMe3)NC6H4CH2N(SiMe3)Li 1 and 2-Li(Si Me3)NC6H4CH2N(SiMe3)Li . THF 2 show that both compounds exist in the solid state as discrete dimers that display an analogous four-rung ladder core, a llowing us to analyse the effect of THF coordination.