A simple polyheterotopic molecular receptor derived from bispyrazolylmethane showing ambivalent allosteric cooperation of zinc(II)

Authors
Brunet, E Juanes, O de la Mata, MJ Rodriguez-Ubis, JC
Citation
E. Brunet et al., A simple polyheterotopic molecular receptor derived from bispyrazolylmethane showing ambivalent allosteric cooperation of zinc(II), EUR J ORG C, (10), 2000, pp. 1913-1922
Citations number
23
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
1434193X → ACNP
Issue
10
Year of publication
2000
Pages
1913 - 1922
Database
ISI
SICI code
1434-193X(200005):10<1913:ASPMRD>2.0.ZU;2-R
Abstract
The preparation of compounds 1-4 as simple systems to display allostery is described. Transport experiments (bulk liquid membrane) of ammonium cations in the presence or absence of ZnI2 in the receiving and donor phases evide nced strong negative or positive allosteric effects of the metal towards am monium complexation, which depended on the relative arrangement of crowns w ith respect to the pyrazole nitrogens.