K. Narayanan et al., Evidence for low dimension chaos in electrically coupled chemical oscillator in batch condition, I J CHEM A, 39(1-3), 2000, pp. 345-355
Citations number
46
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
In the last few years, the study of coupling of chemical reactions has gain
ed immense importance because of the dynamics arising from such a set up is
analogous to that of biological processes. In the present study we have ma
de an attempt to characterize the dynamics observed during the electrical c
oupling of two Belousov - Zhabotinskii (BZ) oscillators in batch condition.
One BZ oscillator is catalysed by cerium and the other by manganese. The c
oupling strength is varied by using external resistances. The possibility o
f existence of deterministic chaos in this reaction is examined by nonlinea
r dynamical techniques such as the estimation of Lyapunov exponent and corr
elation dimension, followed by false nearest: neighbourhood method, surroga
te data and predictability analyses. All the above methods of analysis show
that due to coupling the oscillator catalysed by cerium undergoes more cha
nges in its dynamics from the limit cycle behaviour than the other oscillat
or, i.e., the fast oscillating manganese system affects the dynamics of the
slow oscillating cerium system. Chaos is observed in time series represent
ing the potential difference between the two coupled oscillators. The degre
e of chaos is a function of the external resistance.