Three-dimensional oxalate-bridged heterometal supramolecular complex with a large helical tunnel of 21.191 x 9.294 angstrom(2)

Authors
Shen, HY Bu, WM Liao, DZ Jiang, ZH Yan, SP Wang, GL
Citation
Hy. Shen et al., Three-dimensional oxalate-bridged heterometal supramolecular complex with a large helical tunnel of 21.191 x 9.294 angstrom(2), INORG CHEM, 39(10), 2000, pp. 2239
Citations number
27
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
10
Year of publication
2000
Database
ISI
SICI code
0020-1669(20000515)39:10<2239:TOHSCW>2.0.ZU;2-7
Abstract
The preparation, X-ray crystal structure, and magnetic properties of a nove l three-dimensional oxalate-bridged heterometal supramolecular complex {K[C u(trans[14]-dien)]Cr(ox)(3)}(n) (trans[14]dien = 5,7,7,12,14,14-hexamethyl- 1,4,8,11 -tetraazacyclotetradeca-4, Il-diene; ox = oxalate ion) have been r eported. The magnetic investigation showed that the oxalate-bridged chromiu m(m)-copper(II) units were antiferromagnetically coupled (J = -9.88 cm(-1)) .