The use of quasicrystals as crystal analysers has been studied in monochrom
atic X-ray synchrotron radiation applications. The quasiperiodicity of thei
r structures gives a theoretical third-harmonic rejection factor of up to 5
x 10(-4) when the icosahedral (20,32) Bragg peak is used. This ratio is co
mpared with the intrinsic value for silicon perfect crystals in Bragg confi
guration, namely 2 x 10(-2). This rejection factor may be increased for som
e well defined configurations, as reported elsewhere for the case of period
ic crystals.